Web service is a part of WCF. WCF offers much more flexibility and portability to develop a service when comparing to web service. Still we are having more advantages over Web service, following table provides detailed difference between them.
Features
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Web Service
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WCF
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Hosting
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It can be hosted in IIS
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It can be hosted in IIS, windows activation service, Self-hosting, Windows service
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Programming
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[WebService] attribute has to be added to the class
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[ServiceContract] attribute has to be added to the class
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Model
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[WebMethod] attribute represents the method exposed to client
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[OperationContract] attribute represents the method exposed to client
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Operation
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One-way, Request- Response are the different operations supported in web service
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One-Way, Request-Response, Duplex are different type of operations supported in WCF
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XML
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System.Xml.serialization namespace is used for serialization
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System.Runtime.Serialization namespace is used for serialization
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Encoding
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XML 1.0, MTOM(Message Transmission Optimization Mechanism), DIME, Custom
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XML 1.0, MTOM, Binary, Custom
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Transports
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Can be accessed through HTTP, TCP, Custom
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Can be accessed through HTTP, TCP, Named pipes, MSMQ,P2P, Custom
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Protocols
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Security
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Security, Reliable messaging, Transactions
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